Gmelin Handbook of Inorganic and Organometallic Chemistry Element S S. Schwefel. Sulfur (System-Nr. 9) Ergdnzungsband S-N S-n-Verbindungen/Sulfur-Nitrogen Compounds Part 10, Gmelin S-n-Verbindungen Tl 10, Compounds with Sulfur of Oxide |
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| Author:
| Baumann, Norbert
Fachmann, Hans-Juergen
Jotter, Reimund |
| Editor:
| Baumann, Norbert
Jotter, Reimund
Kubny, Alfons |
| Index by:
| Hettwer, U. |
| Editor-In-Chief:
| Kubny, Alfons |
| ISBN: | 978-3-540-93707-4 |
| Publication Date: | Jan 1994 |
| Publisher: | Springer
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| Book Format: | Hardback |
| List Price: | AUD $3456.95 |
Book Description:
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This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z...
More DescriptionThis volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O,S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been explored.