Synthesis and Application of [2. 2]Paracyclophane Derivatives in Catalysis and Material Science |
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| Author:
| Zippel, Christoph |
| Series title: | Beiträge Zur Organischen Synthese Ser. |
| ISBN: | 978-3-8325-5412-5 |
| Publication Date: | Nov 2021 |
| Publisher: | Logos Verlag Berlin
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| Book Format: | Paperback |
| List Price: | USD $67.50 |
Book Description:
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[2.2]Paracyclophane is a prevalent Ïeâestacked, carbocyclic scaffold with a âeoebent and batteredâe structure. This results not only in a transannular communication but also in a chiral plane within the molecule if at least one substituent is present. These unique properties make this structure synthetically challenging but also scarcely investigated.A new method for enantio-separation based on kinetic resolution was developed, which allows the access to enantiomerically...
More Description[2.2]Paracyclophane is a prevalent Ïeâestacked, carbocyclic scaffold with a âeoebent and batteredâe structure. This results not only in a transannular communication but also in a chiral plane within the molecule if at least one substituent is present. These unique properties make this structure synthetically challenging but also scarcely investigated.A new method for enantio-separation based on kinetic resolution was developed, which allows the access to enantiomerically pure [2.2]paracyclophane-based building blocks. In a liquid crystal templated chemical vapor deposition process, [2.2]paracyclophanyl alcohols containing an additional central chiral element were evaluated for the self-assembly of nanofibers. Furthermore, the cyclopropanation of α-alkyl-α-diazo compounds with a [2.2]paracyclophane-based rhodium tetracarboxylate complex was investigated. Finally, the rigidity, regioselective functionalization, and transannular communication of [2.2]paracyclophane were exploited in the design of heterobimetallic Au(I)/Ru(II) complexes for the study of metal-to-metal interactions.